月光花素甲（I）,（II）整体分子结构的测定.pdfVIP

维普资讯 有_机化学 YOuJIHUAXU~，1989，，146~150拜兜论女 月光花素甲(I)、(Ⅱ)整体分子结构的测定 胡友川 ‘、郭奇珍、 R．Pastor，G．Serratrice2，A．Cambon。，C．Bosso‘ (厦门大学，化学系) S~ucm re Determination of Calonyctin A1and Calonyctin A2 HU You--Chuan ‘，GUO Qi-Zhen，R．Pastor G ．Serratrice~ A ．Cambon。 C．Bosso ‘ (DepartmentoyChemLetry，Xiam~ Univeesity，Xiamen) r Abstract．Using DEPT 0C—NM R． H-H COSY 2D NM R ． H一H NOESY 2D NMR H‘_]0C COSY 2D NM R and positive，negativeFAB-M S techniques thechemicaIcomposition ofa ． plantgrowth substance hasbeen determ ined to be a mixture of tWO homologou glycosides (Calonyctin A land Calonyctin A2) each containing fourrham [1o~ with branching atone of the sugar residues．Calonyctin A idiffersfr0m A2only OO the structure of their agiyco- nes by 28a．m．u，s (—CH2—CH 一 )．The conf uration of foul rhamnoses (one of them hasa—anometiccarbon and therest ) the structur eofthe subtsituentOn sugarD (calIed S)and thelinkagefa~ on among thesix molecularfragmentsin the two glycosidcs show no difference．ThetWO aglyconcsexisting in tWO glycosides (callde AG and AG )and S wereprovde to be 11-hydfoxy hexadecanoic acidicgroup， l1-hydroxy tetradeeanoic acidic group and 2-hydroxy 3-mcthylbutyric acid．respectively by FAB—MS andNM R analyses． Thesix molecular fragmentsin each glycoside are linked together via A 1 ， B，一D2BfCI， D |一AGrAG ) C~-AGrAG )and D3-S． Descriptor ‘plantgrowth regulators structure analysis， nuclcar magnetic resonance． mass spectra glycoside．rhamnosc，calonyctin A 本文对月光花素 甲(CalonyctinA)的整体 有 3个鼠李糖、 1个 3一位碳 上有取代基 的 鼠 分子结构分析加 以完善 并进行总结。 前文 李精和 1个甙元。3个 鼠李糖 (1个 a一异头碳 报道月光花紊 甲是两个分子量相差 28a．m．u