缝隙腐蚀与防护.pdfVIP

Settings of My Documents 缝隙腐蚀与防护 摘要：缝隙腐蚀常发生在腐蚀介质中的金属表面上，是在缝隙和 其他隐蔽的区域内发生的一种局部腐蚀。孔穴、垫片接触面、搭接缝 内、沉积物下、紧固件缝隙内是常发生缝隙腐蚀的地方。凡是依靠氧 化膜或钝化层抗腐蚀的金属特别易发生这种腐蚀。在许多介质中，特 别是含氧的介质中会发生缝隙腐蚀。缝隙腐蚀也是一种电化学腐蚀。 这是由于金属溶解入介质中后便放出电子，如果有氧，特别是有氯离 子，将与电子在水溶液中形成 或 ，使金属不断腐蚀。即使缝 隙中的氧消耗完，但由于氯离子有快速迁移能力，得以使金属在缝隙 中的氯化物浓度增加，即缝隙中加快了腐蚀。 关键词：缝隙腐蚀；原理；特征；影响因素；防护 Abstract: Crevice corrosion often happen in the metal surface corrosive medium, is in aperture and other hidden area of a local corrosion occurred. Caities which act, gasket surface, take a juncture inside, sediment, fasteners within the aperture is often occur crevice corrosion place. All depend on oxidation film or the passivation layer of metal corrosion is especially vulnerable to happen this corrosion. In many media, in particular with the medium oxygen will happen in the crevice corrosion. Crevice corrosion is also a kind of electrochemical corrosion. This is because of the metal dissolved into the medium was released after electronic, if aerobic, especially with the chloride ions, will and electronic in water solution form OH-or H + Cl-and makes the metal constantly corrosion. Even if the crack in the oxygen consumption over, but because the chloride ions have rapid transfer ability, to make metal in. Kyword: Crevice corrosion; Principle; Characteristic; Influencing factors; protection 1. 缝隙腐蚀 1.1. 缝隙腐蚀的定义 缝隙腐蚀常发生在腐蚀介质中的金属表面上，是在缝隙和其他隐蔽的 区域内发生的一种局部腐蚀。孔穴、垫片接触面、搭接缝内、沉积物下、 紧固件缝隙内是常发生缝隙腐蚀的地方。凡是依靠氧化膜或钝化层抗腐蚀 Created by Wlz Settings of My Documents 的金属特别易发生这种腐 蚀。在许多介质中，特别 是含氧的介质中会