Proton conducting membranes based on semi-interpenetrating polymer network of fluorine-containing polyimide and perfluorosulfonic acid polymer via click chemistry》.pdf

Electrochimica Acta 132 (2014) 457–464 Contents lists available at ScienceDirect Electrochimica Acta j o u r na l h o me p a ge : w w w. elsev /locate/electact a Proton conducting membranes based on semi-interpenetrating polymer network of fluorine-containing polyimide and perfluorosulfonic acid polymer via click chemistry Bin Jiang a , Hongting Pu a,∗ , Haiyan Pan a , Zhihong Chang a,b , Ming Jin a , Decheng Wan a,b a Institute of Functional Polymers, School of Materials Science Engineering, Tongji University, Shanghai, 201804, China b Key Laboratory of Advanced Civil Engineering Materials, Tongji University, Ministry of Education, Shanghai, 201804, China a r t i c l e i n f o a b s t r a c t Article history: Fluorine-containing polyimide (FPI) with hydroxyl groups is synthesized from 4,4 -(hexafluoro isopropy- Received 23 January 2014 lidene) diphthalic anhydride (6FDA), 2,2-bis (3-amino-4-hydroxyphenyl) hexafluoropropane (6FAP), and Received in revised form 18 March 2014 4,4 -diaminodiphenyl ether (ODA) via high temperature polycondensation. Thereafter, alkynyl groups Accepted 19 March 2014 are introduced into FPI. During the preparation of the composite membrane, alkynyl groups on FPI react Available online 2 April 2014 with azido