Removal of chlorpheniramine in a nanoscale zero-valent iron induced heterogeneous Fenton system Influencing factors and degradation intermediates》.pdf

Chemical Engineering Journal 284 (2016) 1058–1067 Contents lists available at ScienceDirect Chemical Engineering Journal journal homepage: www.else /locate/cej Removal of chlorpheniramine in a nanoscale zero-valent iron induced heterogeneous Fenton system: Influencing factors and degradation intermediates Lin Wang a, Juan Yang a, Yongmei Li a,b,⇑, Juan Lv a,c, Jinte Zou a a State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, People’s Republic of China b UNEP-Tongji Institute of Environment for Sustainable Development, Shanghai 200092, People’s Republic of China c School of Environmental and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, People’s Republic of China h i g h l i g h t s g r a p h i c a l a b s t r a c t Removal of chlorpheniramine by nZVI/H O was studied for the first 2 2 time. The optimal reaction conditions were determined for chlorpheniramine degradation. Degradation pathway of chlorpheniramine in the nZVI/H2O2 system was proposed. NDMA was formed during the decomposition of chlorpheniramine by nZVI/H O . 2 2 NDMA FP was significantly reduced by nZVI/H O reaction. 2 2 a r t i c l e i n f o a b s t r a c t Article history: Removal of chlorpheniramine in a nanoscale zero-valent iron (nZVI) induced heterogeneous Fenton Received 4 June 2015 system was investigated. The removal efficiency of chlorpheniramine depended on its initial concentra- Received in revised form 6 September