毕业论文-核壳催化剂的制备及其对乙醇电氧化的催化活性.docVIP

学号： 常 州 大 学 毕业论文 （201届） 题 目 学 生 学 院 石 油 化 工 专 业 班 级 应化 校内指导教师 专业技术职务 校外指导老师 专业技术职务 二○一年月 摘要：关键词：；；； The preparation of Co@Pt/NG core-shell catalyst and the electrocatalytic activity of the oxidatio of ethanol Abstract:We took two steps to get Co@Pt/NG core-shell catalyst,meanwhile,the obtained catalyst will go through thermal treatment under the protection of inert gases.After that,they were characterized by high-resolution transmission electron microscopy and X-ray diffraction. The result shows that the structure of the Co@Pt/NG catalyst is core-shell. The metal nanoparticles are uniformly distributed on carbon and the particle size distribution is narrow .Besides, the structure and morphology of the catalyst are also affected by the thermal treatment.We use the cyclic voltammetry(CV) and linear cyclic voltammetry(LSV) to characterize the electrochemical activity of the catalyst and the characteristics and durability of oxidation reduction kinetics.In the electrolyte solution,the Co@Pt/NG obtained shows great electrochemical property,meanwhile,the core-shell structure help to improve the utilization of Pt . The kinetics test shows that the ORR reaction of the catalyst goes on four electronic route.Compared with the commercial catalyst,the core-shell structure catalyst will show a promising future in fuel cells in terms of the durability ,stability and the cost of the catalyst. Keywords: nitrogen-droped graphene,fuel cells, Co@Pt/NG core-shell catalyst,electrochemical property 目 录 摘要······················································· Abstract··················································· 目次······················································· 1.引言····················································· 1.1质子交换膜燃料电池······································ 1.2阴极催化剂研究进展························