加氢脱硫技术-毕业论文设计.docVIP

加氢脱硫技术毕业论文 摘 要 2O3，即将氧化钴和氧化钼负载在活性氧化铝上。这类加氢脱硫催化剂是以Mo的硫化物作为活性组分，以Co的硫化物为助催化剂，以Al2O3为载体所组成的。当金属单独存在时催化活性并不高，只有二者同时存在时，才具有良好的催化活性。在Co-Mo体系中，Co的加入不但对加氢脱硫反应起着促进作用，而且对异构烯烃的加氢还有轻微的抑制作用，相比之下正构烯烃的加氢饱和受到Co的抑制作用更强，因此能达到更好的加氢脱硫的目的。 本文使用智能重量分析仪Intelligent Gravimetric Analyser)测得了不同温度下异戊二烯Isoprene)、1-戊烯1-Pentene)及噻吩Thiophene)在Co-Mo/γ-Al2O3选择性加氢脱硫催化剂上的吸附-脱附等温线及程序升温脱附曲线DTG)并研究了其扩散性能。结果表明：不同吸附质在Co-Mo/γ-Al2O3选择性加氢脱硫催化剂上的饱和吸附量由大到小的顺序为：噻吩 ＞ 异戊二烯 ＞ 1-戊烯；程序升温脱附曲线显示噻吩与该催化剂存在两种吸附作用，即物理吸附和化学吸附，化学吸附形成Co-Mo-S相，可有效的提高加氢脱硫催化剂的选择性，而1-戊烯和异戊二烯在该催化剂上只存在一种弱吸附作用。动力学结果表明三种不同吸附质的相对扩散系数大小顺序为1-戊烯 ＞ 噻吩 ≈ 异戊二烯。关键字：Co-Mo/γ-Al2O3；噻吩；1-戊烯；异戊二烯；吸附Abstract At present the most effective and economical desulfurization method is the hydrodesulfurization (HDS) technology and the key to hydrodesulfurization technology is the hydrodesulfurization catalysts. Now the general composition of the hydrodesulfurization catalyst is Co-Mo/Al2O3, which was prepared by loading cobalt oxide and molybdenum oxide in alumina. This kind of hydrodesulfurization catalyst use Mo-sulfide as active component, Co-sulfide as promotor catalyst, and Al2O3 as the support. The catalytic activity is not high if only one metal active compound exist, but this catalyst showed a good catalytic activity when two active components (Co, Mo) were loaded. In the Co-Mo system, Co is not only promoting the hydrodesulfurization reaction, but also inhibiting the hydrogenation of heterogeneous olefins mildly, at the same time, the hydrogenation saturation of olefins is strongly inhibited by the influence of the Co, which can induce to a better hydrodesulfurization performance. An adsorption-desorption isotherms and temperature-programmed desorption curves of thiophene, 1-pentene and isoprene along with the diffusion coefficients on selective hydrodesulfurization catalyst Co-Mo/γ-Al2O3 were determined by an intelligent gravimetric analyzer (IGA) at different temperatures. The results indicated that: the order of saturated adsorption capacity of thiophene, 1-