苯酚二磺酸类配位聚合物的合成、结构及其性质的研究.pdf

068 Abstract Inthis thesis，two of acid compounds and acidhave 2-hydroxy-5一bromobenzene一1，3．disulfonicbeen andusedto synthesized construct2 1 metal sulfonate the solutionreactionWithdifferent complexesthrough alkalineandsilver salts．These12 exhibiteddiverse complexes zero．，one、two．and three—dimensionalarchitectures．Allt11e andmetal werea11 ligands organiccomplexes characterized byelemental and analyses，IR,PL，TGpowdersinglecrystalX-ray diffraction．Theof thealkalinemetalsand types coordinationmodesofthe ligands rolesonthe playedimportant fmalstructuresofsulfonate structuresare high-dimensional tobeformedwith easily the radiusof increasing alkaline metalsandthe coordinationmodes complicated ofsulfonate groups．The coordination molecules ofNH3 ledtothe0-D the structures structures，on contrary,3-D couldbe obtained withoutthe of molecules．It