《Poly（styrene-co-divinylbenzene）-PAMAM-IDA chelating resin： Synthesis, characterization and application for Ni（II） removal in aqueous.》.pdf

J．Cent．SouthUniv．(2014)21：3479—3484 垒Springer DoI：l0．1007／s11771—0l4—2325—5 Poly(styrene—co—diVinylbenzene)一PAMAM—IDAchelatingresin：Synthesis， characterizationandapplicationforNi(II、lremovalinaqueous LIUYao．chi(~耀驰)，LIXue—nong(李学农) ，WANGChun．zhi(SE春志)’。， KONGXiu(4L秀)，ZHOUGLi．zi(N荔子) 1．CollegeofChemistryandChemicalEngineering，CentralSouthUniversity,Changsha410083，China； 2．BalingCompany，ChinaPetroleum ChemicalCorporation，Yueyang414000，China ◎CentralSouthUniversiytPressandSpringer-VerlagBerlinHeidelberg2014 Abstract：PS．PAMAM—IDAchelatingresinswerepreparedbylow-generationsofpolyamidoamine(PAMAM)andthenchloroacetic acidfunctionalizingcommerciallyavailableammoniatedpolystyrenematrix．topreconcentrateNi from syntheticaqueoussamples． DifferentgenerationsofPAMAM wereused to obtaindifferentchelatingresins。PS．IDA．PS一1．0G B MAM—IDA and PS一2．0G PAMAM．IDA．ThesynthesizedresinswerecharacterizedbyFTIR andelementalanalysis．TheefrectofsolutionPH．kineticstudies． resin1oadingcapaciyt,matrixeffectsetc．．onmetalionadsorptiontoadsorbentphase，werestudiedbybatchmethod．ThePS．1．0G PcMAM。IDAresinwasthemostexcellentadsorbents．withamaximum adsorptioncapacityof(24．09土1．79)mg／gforNi ionat DH=7．Theinteprretationoftheequilibrium datawasgivenbyLangrnuirisothermsmodelandthecorrelationcoemcientvaluesfor PS．IDA．PS一1．0G PAMAM—IDA andPS2．0G PAM AM ．IDAresinswere0．992．0．994and0．987．respectively． Keywords：chelatingresin；polyamidoamine；iminodiaceticacid；properties；Ni(II) temperature and ion—strength upon adsorption 1Introduction equilibrium，kinetics，thermodynamicsandregeneration [4—8]．