《硫杂质对焦反应性的影响及其机理（英文版）》.pdfVIP

Trans. Nonferrous Met. Soc. China 24(2014) 3702−3709 Effect of sulfur impurity on coke reactivity and its mechanism Jin XIAO, Song-yun DENG, Qi-fan ZHONG, Shao-long YE School of Metallurgy and Environment, Central South University, Changsha 410083, China Received 28 April 2014; accepted 25 August 2014 Abstract: Effect of sulfur impurity on coke reactivity was investigated by simulating petroleum coke with low-impurity pitch coke and impurities doping. And its mechanism was discussed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS). The results show that sulfur has strong catalysis on both air and CO2 reactivity of coke in the case of no other impurity interference. Its catalysis is probably realized by triggering organic sulfur→H S→SO →COS and elemental 2 2 sulfur (S )→SO and organic sulfur→H S→COS→S →C S→COS reaction systems during coke−O and coke−CO reactions, x 2 2 x 2 2 2 respectively, which are partly circular with functions of increasing carbon consumption and enlarging coke specific surface area. Key words: coke; reactivity; sulfur impurity; catalysis SORLIE [7] reported that the air reactivity of carbon 1 Introduction anode increased first and then decreased with the