《铬酸钠碱性液中拜耳石的结晶行为（英文版）》.pdfVIP

Trans. Nonferrous Met. Soc. China 24(2014) 3356−3365 Crystallization behaviors of bayerite from sodium chromate alkali solutions Guang-ye 1,2 1 2 1 1 1 1 WEI , Jing-kui QU , Yu-dong ZHENG , Tao QI , Qiang GUO , Bing-bing HAN , Hong-xin ZHAO 1. National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China; 2. School of Materials Science and Engineering, University of Science and Technology, Beijing 10083, China Received 10 October 2013; accepted 25 February 2014 Abstract: In order to clean production of chromium compounds, it is a critical process to remove aluminates and utilize aluminum compounds from artificial chromate alkali solutions. The effects of Na CrO on the neutralization curve, Al(OH) precipitation 2 4 3 efficiency and induction period of bayerite were investigated. The results indicate that the neutralization curve of the artificial chromate alkali solutions shows three distinct regions and its induction period is longer than that of pure sodium aluminate solutions at the same aluminum concentration. And the decreased temperature and volume fraction of CO2 enhance the particle size of bayerite β-Al(OH)3. Bayerite composed of agglomerates of rods and cone frustums was obtained from alkali metal chromate solutions with 28.5% CO2 (volume fraction) at temperatures ranging from 50 °C to 70 °C. Coarse bayerite with particle size (d50) from 24.2 μm to 29.3 μm extremely has few impurities, which is sui