《Syntheses, Structures and Characterizations of Two New Vanadium(V) Complexes [PyH][VⅤO2(C14H9N2O3Br)] and [VⅤO(C14H9N2O3Br)(OCH3)]》.pdfVIP

21 卷6 期 结 构 化 学 JIEGOU HUAXUE Vol. 21, No. 6 2002. 11 Chinese J. Struct. Chem. 629~633 Syntheses, Structures and Characterizations of Two New Vanadium(V) Complexes: [PyH][V O (C H N O Br)] 2 14 9 2 3 and [V O(C H N O Br)(OCH )] 14 9 2 3 3 ZHANG Xiu-Tang ZHAN Xiao-Ping WU Ding-Ming ZHANG Quan-Zheng CHEN Shu-Mei YU Ya-Qin LU Can-Zhong (State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China) ABSTRACT The new oxovanadium ( ) complex, [PyH][VO (L)] 1 (salicyladehyde 5-bromo 2 salicyloylhydrazone is abbreviated as H L; Hpy is protonated pyridine) was obtained from a 2 refluxed solution of VOSO and H L in acetonitrile-methanol-pyridine. Similarly, another new 4 2 complex, [VO(L)(OCH )] 2 was synthesized by refluxing VOSO and H L in methanol-pyridine. 3 4 2 Crystal data for