《Synthesis and Crystal Structure of 2-Hydroxybenzoic Acid [1-(3,5-Dibromo-2- hydroxyphenyl)methylidene]hydrazide Methanol》.pdfVIP
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《Synthesis and Crystal Structure of 2-Hydroxybenzoic Acid [1-(3,5-Dibromo-2- hydroxyphenyl)methylidene]hydrazide Methanol》.pdf
26卷5剜 结 构 化
2鲤2:墨 Q地坚Z堑型噬Q幽: §垒2=墨苎Q
andC Structureof
SynthesisrystaI
2一Hydroxybenzoic
Methanol①
hydroxyphenyl)methylidenelhydrazide
Ⅵ已气-NG LI PU
Nong瞎 Jing·PingYh-Ling
nnd
ISchoolt可Chemicnl8ioiogicQlEngineering.LQnzhoH
JinotongUniverSity。Lnnzhotl,13Q∞Q。Chin∞
ABSTRACTAnewSchiffbase
cornpound,2-hydroxybenzoic
been t11e
phenyl)metllylidene】hydrazidemetllanol(C14HIoBr2N203·CH30H),hassynmesizedby
condensationof alld acid ina
equim01ar3,5-dibromosalicylaldehyde2-hydroxybenzoichydrazide
metllanoIsolution.Thewascharacterizedelemental
compound by analysis,IRspectra,andsingle—
difh.action.TheconsistsofaSchifrb弱e acid
c巧stalX—ray compound moie哆2一hydroxybenzoic
alatticemeth绷01molecule.The
【l-(3,5一dibromo-2_hydroxyphenyl)me吐桫Iidene】hydr配idc扑d
tothemonoclinic
c科stalbelongs systcm,spacegroup
0.71073 andwR=0.0963.Atotalof3445
A,∥=4.872mm一,只000)=880,尺=0.0458 unique
reflectionswere which2236 we他observed.As m01ecule
conected,of with,2吠D expected,the
tlle arc
C=Ndoublebond.The细obenzene
adoptsa,r口册configuration‘about ringsnearlycoplanar
the is the
combined
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