《Synthesis and Crystal Structure of an Infinite 1D Zigzag Chain Compound (dimbH+)(ClO4-) and Its Comparison with (dimb)#183;2H2O (dimb =1,3-Di(imidazol-1-ylmethyl)-5-methylbenzene)》.pdfVIP
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《SynthesisandCrystalStructureofanInfinite1DZigzagChainCompound(dimbH+)(ClO4-)andItsComparisonwith(dimb)amp;#183;2H2O(dimb=1,3-Di(imidazol-1-ylmethyl)-5-methylbenzene)》.pdf
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22卷4朋 结构化学 JlEGoUHUAxUEl V0l_22.No.4
2003.7 Ch』,lF5F』 Sl删“. C船m 439—443
and StructureofanInnIlite1D
SynthesisCrystal
z】嗜郾曙Chain
Its
Comparison
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YAO MA HUANG Shao—Hua6∞
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8(D印d一珊Pnf。,∞删f甜供L“叫dng乃d如P坩。螈P,L“倒d愕47J022,函抽d)
。旧oord}mfioHChm}se@I雌m¨把.stn把KeyL娃bomtoq对coominntton
2、∞93,Chinn、
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Arlewimidaz01ium f如maaexible
ABSTRACT compound,C15H17N4-C104,wasprepared
bidentateof characterized
ligand1,3·di(imidazol一1-ylmethyl)一5一methylbenZene,andbyx—ray
isof 6ll(4)
analysis.Itonhorhombic,spacegmup^埘d
A,y=1644.4(7)A。,D,=1.425
g,cm’,Z=4,M,=352.78,p(MoⅣ∞j
for1128observed
and¨稍=0.1187
S=1.036,t11e疗naJ尺=0.052l
inflniteone-dimensionalchajnisfonTledN—H…N in陀ractions
zigzdg by hydmgenbonding
hetweenthejmjdazollumsaltca60ns
salt,hydmgenbonding
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l INTRODUCTIoN rotaxane,helicates,cavi廿esand,br
unitsand some
cycles,cage-likehoneycombs,and
the of o血ershavebeen onmeir
rationaI aIld studied
Recently design widely
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