《Synthesis and Crystal Structure of Bisaqua-[N,N′-bis(3,5-dichlorosalicylidene)-1,3-diaminopropano]zinc(Ⅱ)》.pdfVIP
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《Synthesis and Crystal Structure of Bisaqua-[N,N′-bis(3,5-dichlorosalicylidene)-1,3-diaminopropano]zinc(Ⅱ)》.pdf
25 卷9 期 JIEGOU HUAXUE Vol. 25, No. 9
2006. 9 Chinese J. Struct. Chem. 1043~1046
Synthesis and Crystal Structure of Bisaqua-
[N,N ΄-bis(3,5-dichlorosalicylidene)-
1,3-diaminopropano]zinc(II)
YOU Zhong-Lu HAN Xiao WANG Jia CHI Jing-Yun
(Department of Chemistry and Chemical Engineering,
Liaoning Normal University, Dalian 116029, China)
ABSTRACT The title mononuclear zinc(II) complex [Zn(BCDP)(H O) ] (BCDP = N,N ΄-bis(3,5-
2 2
dichlorosalicylidene)-1,3-diaminopropane) was prepared and characterized by elemental analysis,
IR spectra and single-crystal X-ray diffraction. The crystal belongs to the orthorhombic system,
3
space group Pnma with a = 7.887(1), b = 23.788(2), c = 10.295(4) Å, Z = 4, V = 1931.5(8) Å , D =
c
3 1
1.786 g/cm , M = 519.49, λ(MoKα) = 0.71073 Å, µ = 1.853 mm , F(000) = 1048, R = 0.0464 and
r
wR = 0.0918. A total of 2273 unique reflections were collected, of which 1570 with I 2σ(I) were
observed. The molecule
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