《Synthesis of MgO-Al2O3ZSM-5 by Solid State Reaction for Propane Dehydrogenation》.pdfVIP

China Petroleum Processing and Petrochemical Technology Catalyst Research 2013, Vol. 15, No. 3, pp 50-56 September 30, 2013 Synthesis of MgO-Al O /ZSM-5 by Solid State Reaction for 2 3 Propane Dehydrogenation Zhou Shijian; Zhou Yuming; Sheng Xiaoli; Zhang Yiwei; Zhang Zewu; Shi Junjun; Kong Jie (School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189) Abstract : Solid-state grinding is a simple and effective method to introduce guest species into the channels of micro- porous materials through filling. The structure and the surface acidity of the materials were obtained from BET isotherms and NH3-TPD, respectively. XRD, UV-vis, UV diffuse-reflectance, and TEM were used to characterize the phases, and the morphology, respectively. The clustered layers of MgO-Al O phases were formed in the internal pore surface and were highly 2 3 dispersed inside the channels of the ZSM-5 host. So the volume of MgO-Al O /ZSM-5 composite was larger than the ZSM- 2 3 5 zeolite itself and some mesoporous channels appeared when Mg/Al species entered the channels. Meanwhile, new acid sites emerged in MgO-Al O /ZSM-5 composite and the acid amount of the sample changed. The improved Pt dispersion and the 2 3 increased acid content would cause the increase of propane conversion and the modification of selectivity during the reaction. Key words: MgO-Al O ; solid state reaction; PtSn; propane dehydrogenation 2 3 1 Introduction