Influences of water treatment agents on oil-water interfacial properties of oilfield produced water-论文.pdf

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Influences of water treatment agents on oil-water interfacial properties of oilfield produced water-论文.pdf

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!!：cll( ：兰 4l5 D0I10．1007／s12l82—0l3-0290—5 Influencesofwatertreatmentagentsonoil--water interfacialpropertiesofoilfieldproducedwater GuoJixiang ，CaoJingjing，LiMingyuanandXiaHaiying E‘nhancedOilRecoveryInstitute，ChinaUniversityofPetroleum，Beijing102249，China EngineeringTechnologyInstituteofSouthwestPetroleum BranchCompany,Sinopec，Sicuan618000，China ◎ChinaUniversiytofPetroleum (Beijing)andSpringer-VerlagBerlinHeidelberg2013 Abstract：Theemulsionstabilityofoilfieldproducedwaterisrelatedtotheoil·waterinterfacialfilm strengthandthezetapotentialoftheoildroplets．Weinvestigatedtheeffectsofwatertreatmentagents (corrosioninhibitorSL．2．scaleinhibitorHEDP’germicide1227，andflocculantpolyaluminium chloride PAC、onthestabilityofoilfieldproducedwater．Theinfluenceofthesetreatmentagentsonoil—water interfacia1propertiesandthemechanism oftheseagentsactingontheoilfieldproducedwaterwere studiedbymeasuringtheinterfacialshearviscosity,interfacia1tensionandzetaelectricpotentia1．The resultsindicatedthatthescaleinhibitorHEDPcouldincreasetheoil-waterinterfacialfilm strength，andit couldalsoincreasetheabsolutevalueofthezetapotentialofoi1rdoplets．HEDPplayedanimportantrole inthestabilityoftheemulsion．Polyaluminumchloride(PAC)reducedthestabilityoftheemulsionby considerablydecreasingtheabsolutevalueofthezetapotentialofoilrdoplets．CorrosioninhibitorSL-2 andgemr icide1227coulddecreasetheoil—waterinterfacialtension．whereastheyhadlittleinfluenceon oil．waterinterfacialshearviscosityandoil—waterinterfacia1electricityproperties． Keywords：Waterrteatmentagents，oil-waterinterfacialproperties，emulsionstabiliyt,oilfieldproduced w ater 1Introduction water(Santinietal，2010；Allensonetal，20l1：Chenetal， 2007)．Tbinvestigatetheeff．ectofwatertreatmentagents Waterfl