大分子表面改性剂地设计合成和其对聚苯乙烯表面极性地改性研究.pdf

macromolecular surface modifier. The attenuated total reflectance Fourier transform infrared spectroscopy(ATR-FTIR) and contact angle measurement were used to detect the surface structure and surface properties. It was indicated the influence of contact medium on the selective migration of polyether silicone oil was much important. The glass induced more polyether chain segments on the polystyrene surface and the air induced more silicone oil chain segments on its surface. The selective aggregation of the polyether silicone oil(PSO) on the surface of the polystyrene films was investigated by using the contact angle measurement and the attenuated total reflectance Fourier transform infrared spectroscopy. By utilizing the “surface target” effect of the chain segments of the silicone oil, the applied efficiency of the macromolecular surface modifier(PSO) was enhanced greatly. Due to the good hydrophilicity of polyether chain segment, the surface free energy(γ) of the blends was enhanced 180 ％ and the polar portion of its γ increased nine times. Because the chain segments of silicone oil could preferential aggregate on the surface of the PSO/PS blends, it led the polyether chain segments migrated on the surface of the films which took the climacteric role in improving the hydrophilicity of the films. It also found that the preferential surface migration of PSO was heavily depended on the surface properties of the contact medium. Compared with the different mechanisms of the surface migration, the inducement of polar groups on substrates (glass or polyimide) made more chain segments of polyether aggregated on the blends surface and the polar portion of the surface energy of the films was increased greatly. Whatever the samples were annealed by polyimide or polytetrafluoroethylene, the concentratio