水性聚氨酯的制备和性能的研究.pdf

18IIIIIIIIIIIIHHIIIHIII Y2338121 Abstract Inthis seriesofwaterborne bya paper，a polyurethane(WPU)wereprepared ofemulsionwasreseacheda rotational prepolymerizationprocess．Theviscosity by the ofthemolecularanddistributionofPU GPC viscometer；westudychange weight by was beforeandafter sizeanddistributionabserved DLS；we extending；theparticle by study thekineticsof and behaviorofPU an prepolymermicrophaseseparation byFT-IR；using toreseachonthe stattionofthe solidcontent opticalmicroscope particleexisting high thattheDMPAcontent、themolecularof emulsion；we soft havethe analysis weight segment influenceontheemulsionand ofPU． stabilityproperties aseriesofthesolidcontentof30％WPUbasedonDMPA、CD2000、IPDI、 (1)Wesynthesis EA．We of IPDAand reseachthekinetics andtheinfluenceofDMPAcontent、the prepolymer ofchainextender、chainextendercoefficientonthe ofPU．Theresults type performance thatthe is at for show NCOvaluereached80·85。C 5hours：whenthecontentof designed DMPAis5％，the ofWPUis thechainextension is viscosity lowest；when coefficientO．95， thetensile is strengthoptimi