高碱高钙受抑黄铁矿与毒砂浮选分离的活化行为研究.pdfVIP

Abstract Abstract AAbbssttrraacctt The precondition of separation high lime-depressed pyrite and arsenopryite by flotation is reactivating, while the traditional activators of sulfur ore such as sulfuric acid have lots of advantages. So it is necessary to develop the new activator for the separation lime-depressed pyrite and arsenopyrite. In this paper, the lime-depressed pyrite and arsenopryite pure minerals as the research object, the activation performance of six activators (sulfuric acid, oxalic acid, copper sulfate, ferrous sulfate, aluminum sulfate, ammonium bicarbonate) and their combination activator were studied in different systems. On the view of technique and economy, ammonium bicarbonate was thought effective and pollution-free, and a good result of the flotation separation of artificial mixture ore can be obtained by using it. The activation mechanism of ammonium bicarbonate was studied by electrochemical (cyclic voltammetry), found the ammonium bicarbonate can obviously activate lime-depressed pyrite, while the activation relatively weak for arsenopryite, as the cyclic voltammet ry curve shown, along with the increase of ammonium bicarbonate, the cyclic voltammetry curve of lime-depressed pyrite shown that oxidation peak of the corresponding peak current and potential peak were decrease significantly, starting oxidation potential rise, pyrite surface is restored; while cyclic voltammetry curve of lime-depressed arsenopryite shown that oxidation peak of the corresponding peak current and potential peak decrease unconspicuous, arsenopryite surface can be restored while large amount of ammonium bicarbonate. The mechanism of ammon