某钨钼尾矿二次源综合利用的研究.pdfVIP

II 摘 要 矿产资源作为一种不可再生的资源其蕴藏量正随着人类对矿产资源的需求以迅 猛的速度逐年减少，预测21世纪全世界将采出已查 明的大部分有色金属量的一半. 因 此，开发利用贫矿和尾矿对国家矿业的可持续发展具有重要意义。 （1）本研究针对目前我国尾矿的严重污染问题，以某钨钼尾矿为研究对象，采 用单一浮选方法将白钨矿和辉钼矿两种有价金属从尾矿中分选出来，实现了矿山尾 矿二次资源综合利用的目的。获得理想的试验室选别指标：原矿含Mo0.012% ， WO 0.17% 。钼精矿含Mo46.12% ，钼金属回收率76.87% ，白钨精矿含WO 61.09% ， 3 3 WO3 回收率78.10% 。 （2 ） 针对该矿地理条件和尾矿库物料特性将白钨常温浮选工艺成功运用于尾 矿综合利用。着重对采用731氧化石蜡皂常温浮选法回收白钨矿 的工艺条件进行了详 细的试验研究。白钨粗选采用碳酸钠与水玻璃的组合改善并获得较高品位白钨粗精 矿，白钨粗选作业富集比高达60 以上，精选使用PY 与水玻璃组合改善了精选泡沫难 控制、难操作的困难。 （3 ）对水玻璃、油酸、氧化石蜡皂这些浮选药剂从溶液化学的角度做了简单的 机理分析 。对氧化石蜡皂的改性进行了简单归纳，有利于该药剂适用适应性的提高。 （4 ）731氧化石蜡皂常温白钨浮选工艺简单，操作方便，选矿成本低，用于尾 矿资源综合利用具有良好前景。 关键词：白钨矿；辉钼矿；尾矿利用；常温浮选 I Abstracts As unreproducible resources, storage of mineral resources reducing rapidly year by year with the increasingly demand of the resources. It was predicted that half of the nonferrous metal which have been found out will be exploited by 21th century. So the development and utilization of low-grade ore and tailing is critical to the national mining industry’s sustainable development. In recent years, a lot of research have been put on the field, and parts of the achievements has been applied to commercial run. It gained a good effects of economy, environment and society. (1)This research concentrate on the seriously pulltion problem of tailing in our country. The mineral sample used in this research was sampled by scheelite-molybdenum tailing of a mineral processing plant. This research confirmed scheelite-molybdenum bulk flotation- separation to deal with the tailing.The experiments showed good recovery rates ：Mo grade is 46.12% in molybdenum concentrate and recovery rate is 76.87% ；WO3 grade