白光发射ZnS纳米微粒及其体相材料.pdfVIP

Colloids and Surfaces A: Physicochem. Eng. Aspects 434 (2013) 213–219 Contents lists available at SciVerse ScienceDirect Colloids and Surfaces A: Physicochemical and Engineering Aspects j o u r n a l h o me p a ge : w w w. elsev /locate/cols urfa Blue-light-emitting surface-functionalized ZnS nanoparticles and their transparent polymer nanocomposites with near-white light emission Bingxin Liu, Qianqian Liu, Cuiyan Tong, Xiaodan Lü, Changli Lü ∗ Institute of Chemistry, Northeast Normal University, Changchun, 130024, PR China h i g h l i g h t s g r a p h i c a l a b s t r a c t • ZnS-BOX NPs with strong blue- BOX ligand was firstly used to decorate ZnS NPs to fabricate the blue-light emission ZnS-BOX NPs. The emission have been successfully syn- near-white light-emission transparent nanocomposites were successfully fabricated by integrating ZnS- thesized. BOX NPs and rhodamine 6G into polymer matrix by in situ bulk polymerization. • ZnS-BOX NPs were integrated into the polymer to fabricate bulk nanocomposites. • Near-white light nanocomposites were obtained from ZnS-BOX NPs and rhodamine 6G. a r t i c l e i n f o a b s t r a c t Article history: 2-(2-Hydroxyphenyl)-benzoxazol (BOX) functionalized ZnS nanoparticles (ZnS-BOX NPs) with blue-light Received 17 January 2013 emission have been successfully synthesized. The ZnS-BOX NPs can be successfully added into the poly- Received in revised form 10 May 2013 mer matrix by in situ bulk polymerization to fabricate t