生产源区环境中溴环十二烷及其对人群健康影响的研究.pdfVIP

该地区人口出生性别比的变化可能与人体中高水平的HBCD具有某 种关联。 关键词：六溴环十二烷，土壤，植物，人血清，甲状腺，出生性别比 ㈣Y……1 ㈣8帆2帆0洲5Ⅲ9㈣9 ABSTRACTS HBCDhasbeen insouthcoastareaofLaizhou produced Bay, in littleisknownabouttheHBCD China，but Shandongprovince levelofenvironmentandresidentstothese set exposure compounds．We outtoassess healthrisksofHBCDinsouthcoastareaofthe potential Laizhou theconcentrationsofHBCDin Baybydetermining soil，plants andhumanserum samples． Anewmethoddedicatedtotracelevelmeasurement of仅-，13-and soil acceleratedsolventextraction—ultra samplesby performanceliquid ion mass chromatography·-electrospraysource·-triplequadrupole been soil spectrometry(ASE—UPLC—ESI-MS／MS)hasdeveloped．Eight andtwelve collectedfromthisareawere samples plantsamples analyzed andallthethreediastereomerscouldbe identifiedand consistently the ofHBCDinlocalenvironment． quantified，indicatingpresence EHBCDconcentrationsfrom2．80to23849．20 ranged ng／g(dryweight) insoil 1．40to6477．50 samples，and ng／g(wetweight)inplantsamples． Diastereomerratiosinsoiland werebothinnormal samples plant