Hydrochemistry of the Natural Low pH Groundwater in the Coastal Aquifers near Beihai, China.pdfVIP
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OceanUniv.China(OceanicandCoastalSeaResearch)
D0I10.1007/sl1802—015-2631.z
ISSN 1672—5182,201514(3):475—483
http://www.ouc.edu.cn/xbywb/
E-mail.xbywb@ouc.edu.cn
HydrochemistryoftheNaturalLow pH Groundwaterin
theCoastalAquifersnearBeihai,Chnia
ZHOU Xun)’)’ SHENYe), ZHANGHua¨SONG Chao¨LIJingwei¨
, , , , ,
andLIU Yan)
1)SchoolofWaterResourcesandEnvironment,ChinaUniversityofGeosciences(Beijing),Bejiing100083,
P.R.( ina
2)KeyLaboratoryofGroundwaterCirculationandEvolution(ChinaUniversiytofGeosciences(Bejiing)),
MinistryofEducation,Beijing100083,P.R.China
(ReceivedMarch26,2014;revisedJuly1,2014;acceptedJuly23,2014)
@ OceanUniversityofChina.SciencePressandSpringer-VerlagBerlinHeidelberg2015
Abstract NaturalweakacidicgroundwateroccursintheunconfinedandconfinedaquifersconsistingofQuaternaryandNeogene
unconsolidatedsedimentsnearBeihaiinsouthem Guangxi.China.UndernaturalconditionsthegroundwaterhaslowTDS(1essthan
200mgL-1)andlowconcentrationsoftraceelements(1essthan100ggL_。1withadeceasingtendincontentsoftheLanthanides(rare
earthelements,lessthan1ugL-。)towardshigheratomicnumber.ThegroundwaterrangesinpH from 3-33to7.0withanaverage
valueof5.12(evenlowerthanthatoflocalrainwater,5.88).pHvaluesinthegroundwaterareabithigherinrainyseasonsthanthose
indry seasonsanddonotshow significantincreasingordecreasingtrendwithtime.TheaveragepH valueinrgoundwaterinthe
confinedaquifersisevenabitlowerthanthatintheunconfinedaquifer.Comprehensiveanalysesofthegroundwaterenvironment
suggestthatH inthegroundwatermaybederivedfrom dissociationOfH,CO ,releaseoftheabsorbedH O inclaylayersandthe
acidityofrainwater.TheH,CO,inthergoundwatermaybeformedbydissolutionofC0,ro、.M ineralsintheunconsolidatedsediment
arepredominatedbyquartzwithsmallamountofclayminerals.Thesedimentsundergoingalong.termweatheringcontainlow levels
ofsolubleconstitutes.Lackofalkalinesubstancesinthegrou
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