近红外光谱对小麦产地来源的判别分析.pdfVIP

中国农业科学 2011,44(7): 1451-1456 Scientia Agricultura Sinica doi: 10.3864/j.issn.0578-1752.2011.07.018 近红外光谱对小麦产地来源的判别分析 赵海燕，郭波莉，魏益民，张 波，孙淑敏，严军辉，张 磊 （中国农业科学院农产品加工研究所/农业部农产品加工与质量控制重点开放实验室，北京 100193） 摘要：【目的】对不同产地来源小麦的近红外光谱进行判别分析，为小麦的产地鉴别提供一种新方法。【方 法】应用近红外光谱分析仪检测2007/2008 年度和2008/2009 年度中国小麦主产区河北省、河南省、山东省和陕 西省共240 份小麦籽粒样品，对近红外光谱数据分别进行均值标准化、一阶求导和多元散射校正(MSC)处理后，利 用偏最小二乘判别分析法(DPLS)分析预处理后的数据。【结果】2007/2008 年度小麦籽粒样品总体正确判别率为 87.5%，2008/2009 年度样品总体正确判别率为91.7%；用2007/2008 年度样品所建模型来预测2008/2009 年度的 样品，结果总体正确判别率为48.3%；两年样品混合后，总体正确判别率为82.5%。【结论】不同地域来源小麦的 近红外光谱特征有显著差异，但其受品种和年际因素影响较大，判别模型的稳定性有待进一步提高。 关键词：小麦；产地；近红外光谱；DPLS Identification of Geographical Origins of Wheat with Discriminant Analysis by Near Infrared Spectroscopy ZHAO Hai-yan, GUO Bo-li, WEI Yi-min, ZHANG Bo, SUN Shu-min, YAN Jun-hui, ZHANG Lei (Institute of Agro-Food Science Technology, Chinese Academy of Agricultural Sciences/Key Laboratory of Agricultural Product Processing and Quality Control, Ministry of Agriculture, Beijing 100193) Abstract ：【Objective 】A new method was developed for identification of the geographical origins of wheat with discriminant analysis by near infrared reflectance spectroscopy (NIRS) . 【Method 】A total of 240 wheat kernel samples collected in 2007-2008 and 2008-2009 from Hebei, Henan, Shandong and Shaanxi provinces of China were analyzed by NIRS. After normalization, first derivative and multiplicative scattering correction (MSC) pre-treatment of wheat kernel spectral data, discriminant partial least squares analysis (DPLS) was applied to classify the geographical origins of these samples. 【Result 】 There were 87.5% and 91.7% of wheat kernel samples collected in 2007-2008 and 2008-2009 were correctly classified respectively, the tot