Characteristics of coal re-oxidation based on microstructural and spectral observation.pdfVIP

InternationalJournalofMiningScienceandTechnology25(2015)749-754 一 ■ Characteristicsofcoalre—oxidationbasedonmicrostructural CrOSSMark andspectralobservation LiangYuntao 一．TianFuchao ．b一 LuoHaizhubTangHuib ． ， School哦safetyEngineering,ChinaUniversityoiMining琢Technology,Xuzhou221116,China StateKey~boratory CoalMineSafeytTechnology．ChinaCoalTechnology8Engineering GroupofShenyangResearchInstitute，Shenyang 110016,China A R T IC L E lN F O A B S T R A C T Articlehistory： lnordertoinvestigatethecharacteristicsofre—oxidationofresidualcoalingoafsinclosecoalseam min— Received12January2015 ing．scanning electronmicroscopeand infrared spectrometerareused tostudy thechangesofcoal Receivedinrevisedform 5April2015 microstructureandchemicalreaction offunctionalgroupsofeightcoalsamplesatdifferentranks． Accepted 10May2015 Resultshowsthatafterinitialoxidation。thesurfacemorphologyofporearedifierent．andtheporosity Availableonline22August2015 ofcoalisincreasedandtheoxygenadsopr tioncapacityofcoalisimproved．Thechangeofcoalmolecular stm ctureandpresenceofalargeamountofactiveoxygen-containingfunctionalgroupsleadtoincreasing Keywords： tendencyofcoalc0furtheroxidation．Inaddition．thehigherleveroftheinitialoxidationis．theeasierthe Spontaneouscombustionofcoal