不同煤种部分气化生成多环芳烃的试验研究.pdfVIP

第 25 卷 第 2 期 中 国 电 机 工 程 学 报 Vol.25 No.2 Jan. 2005 2005 年 1 月 Proceedings of the CSEE ©2005 Chin.Soc.for Elec.Eng. 0258-8013 (2005) 02-0156-05 TK229 A 470 20 文章编号： 中图分类号： 文献标识码： 学科分类号： ⋅ 三种煤的部分气化生成多环芳烃的试验研究 周宏仓，金保升，仲兆平，黄亚继，肖 睿 ( 东南大学洁净煤发电与燃烧技术教育部重点实验室，热能工程研究所，江苏省 南京市 210096) EXPERIMENTAL STUDY ON POLYNUCLEAR AROMATIC HYDROCARBONS EMISSION FROM PARTIAL GASIFICATION OF THREE TYPES OF COALS ZHOU Hong-cang ，JIN Bao-sheng ，ZHONG Zhao-ping ，HUANG Ya-ji ，XIAO Rui (Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education ， Thermoenergy Engineering Research Institute ，Southeast University，Nanjing 210096 ，Jiangsu Province, China ) ABSTRACT ：Polynuclear aromatic hydrocarbons (PAHs) are 蒸气为气化剂的3种煤部分气化试验，采用高效液相色谱 considered to be a group of compounds that pose potential 法(HPLC)对煤气化产物中被美国环保署(US EPA)指定的16 health hazards since some PAHs are known as mutagens and 种PAHs进行了测定，研究了煤部分气化过程中煤自身性质 carcinogens. PAHs released from coal gasification have 对多环芳烃生成和赋存规律的影响。试验结果表明：煤部分 received considerable attention. Three types of coals were 气化PAHs生成量高于原煤PAHs含量(徐州烟煤除外) ；原煤 gasified partially in a bench-scale atmospheric fluidized bed 固定碳和硫含量增加，煤部分气化PAHs生成量先增后降， gasifier by using air and steam as gasifying medium. The 16 挥发分含量增加，PAHs生成量却呈现出相反的变化规律； PAHs specified by US EPA in the products of coal partial 提高灰分含量或采用低发热量原煤，可以降低煤部分气化 gasification were analyzed by high performance liquid PAHs生成。 chromatography (HPLC). The aim of this work is to study the 关键词：热能动力工程；