a novel difference between strong liquids and fragile liquids in their dynamics near the glass transition：在玻璃化转变附近，强液体与易碎液体的新区别.pdfVIP

Physica A 442 (2016) 1–13 Contents lists available at ScienceDirect Physica A journal homepage: /locate/physa A novel difference between strong liquids and fragile liquids in their dynamics near the glass transition Michio Tokuyama a,∗, Shohei Enda b , Junichi Kawamura a a Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577, Japan b 13-36-18, Towada City, Aomori, Japan h i g h l i g h t s • The dynamics of fragile liquids and that of strong liquids is compared consistently. • A novel difference between their dynamics is found near glass transition. • Existence of master curve in each type of liquids is proposed. a r t i c l e i n f o a b s t r a c t Article history: The systematic method to explore how the dynamics of strong liquids (S) is different from Received 12 May 2014 that of fragile liquids (F) near the glass transition is proposed from a unified point of Received in revised form 11 June 2015 view discussed recently by Tokuyama. The extensive molecular-dynamics simulations are Available online 8 September 2015 performed on different glass-forming materials. The simulation results for the mean-nth displacement Mn (t) are then analyzed from the unified point of view, where n is an even Keywords: (α) Diffusion coefficient number. Thus, it is first shown that in each type of liquids t