a series of homoleptic bis(phthalocyaninato) rare earth sandwich complexes with large two-photon absorption cross-section：一系列的配双（酞菁）稀土夹心配合物具有大的双光子吸收截面.pdfVIP

Dyes and Pigments 122 (2015) 346e350 Contents lists available at ScienceDirect Dyes and Pigments journal homepage: /locate/dyepig A series of homoleptic bis(phthalocyaninato) rare earth sandwich complexes with large two-photon absorption cross-section a, b, 1 a, 1 a c a, * Ning Sheng , Dahui Liu , Bing Gu , Jun He , Yiping Cui a Advanced Photonics Center, Southeast University, Nanjing 210096, China b Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu, 273155, China c School of Physics and Electronics, Central South University, Changsha, 410012, China a r t i c l e i n f o a b s t r a c t Article history: The third-order nonlinear optical properties of a series of homoleptic substituted phthalocyaninato rare Received 5 June 2015 earth double-decker complexes were experimentally investigated by the Z-scan technique at the Received in revised form wavelength of 800 nm. All complexes were revealed to exhibit large two-photon absorption cross- 7 July 2015 sections. The measured two-photon absorption values of these complexes remain constant at different Accepted 10 July 2015 laser intensities, indicating nonlinearity is originated from pure two-photon absorption behavior. In Available online 18 July 2015