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a simple method for the enrichment of bisphenols using boron nitride：用氮化硼双酚富集的一种简单方法
Food Chemistry 194 (2016) 149–155
Contents lists available at ScienceDirect
Food Chemistry
journal homepage: www.elsevier .com/locate/foodchem
A simple method for the enrichment of bisphenols using boron nitride
Martin Fischnaller a, Rania Bakry a,⇑, Günther K. Bonn a,b
a Institute of Analytical Chemistry and Radiochemistry, Leopold-Franzens University of Innsbruck, Innrain 80-82, 6020 Innsbruck, Austria
b ADSI-Austrian Drug Screening Institute, Innrain 66A, Innsbruck, Austria
a r t i c l e i n f o a b s t r a c t
Article history: A simple solid-phase extraction method for the enrichment of 5 bisphenol derivatives using hexagonal
Received 16 February 2015 boron nitride (BN) was developed. BN was applied to concentrate bisphenol derivatives in spiked water
Received in revised form 21 July 2015 samples and the compounds were analyzed using HPLC coupled to fluorescence detection. The effect of
Accepted 23 July 2015
pH and organic solvents on the extraction efficiency was investigated. An enrichment factor up to 100
Available online 26 July 2015
was achieved without evaporation and reconstitution. The developed method was applied for the deter-
mination of bisphenol A migrated from some polycarbonate plastic products. Furthermore, bisphenol
Keywords:
derivatives were analyzed in spiked and non-spiked canned food and beverages. None of the analyzed
Bisphenols
Boron nitride
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