水热处理对我国典型褐煤气化特性的影响.pdfVIP

第33 卷 第32 期 中 国 电 机 工 程 学 报 Vol.33 No.32 Nov.15, 2013 14 2013 年11 月15 日 Proceedings of the CSEE ©2013 Chin.Soc.for Elec.Eng. 文章编号：0258-8013 (2013) 32-0014-07 中图分类号：TQ 536 文献标志码：A 学科分类号：470·10 水热处理对我国典型褐煤气化特性的影响 葛立超，张彦威，应芝，王智化，周俊虎，岑可法 (能源清洁利用国家重点实验室(浙江大学) ，浙江省 杭州市 310027) Influence of the Hydrothermal Dewatering on the Gasification Characteristics of Typical Chinese Lignite GE Lichao, ZHANG Yanwei, YING Zhi, WANG Zhihua, ZHOU Junhu, CEN Kefa (State Key Laboratory of Clean Energy Utilization (Zhejiang University), Hangzhou 310027, Zhejiang Province, China) ABSTRACT: The influences of hydrothermal dewatering 的趋势。煤质结构深度变化和煤阶的上升使得改性后褐煤的 (HTD) performed at different temperatures on the gasification 气化特性曲线向高温区移动，碳转化率达到 50%时的气化 characteristics of typical lignites with different metamorphic 温度上升。动力学计算结果表明，经过水热改性后气化反应 grades in China were investigated in this paper. Results show 活化能上升，反应级数发生变化。较高的水热处理终温和相 that the upgrading process significantly decreases the inherent 对较低的原煤煤阶都使得水热脱水改性的效果更为显著。 moisture at a maximum degree of 87.31% and oxygen content, 关键词：褐煤；脱水改性；水热；煤气化；煤阶 and increases calorific value and fixed carbon content. According to the oxygen/carbon ratio parameter, the coal rank 0 引言 increases. The complex changes occurred on coal structure [1] 我国煤炭资源禀赋条件差 ，褐煤为主的低阶 during the HTD process lead to pore size of coal char develop 煤储量巨大，随着煤炭开采规模的扩大、开采水平 to the microporous region, and the surface area and v