Optimum High-Quality Ceramic Support like SiC, AI203 & TiO2 for Cobalt as a Very Active Metal for Fisher-Tropsch-Synthesis in a Fixed Bed Reactor Configuration.pdfVIP
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Optimum High-Quality Ceramic Support like SiC, AI203 & TiO2 for Cobalt as a Very Active Metal for Fisher-Tropsch-Synthesis in a Fixed Bed Reactor Configuration.pdf
JournalofEnergyandPowerEngineering9(2015)141—148
doi:10.17265/1934.8975/2015.02.003
一 塔
Optimum High—QualityCeramicSupportlikeSiC,AI203&
Ti02forCobaltasaVeryActiveMetalfor
Fisher--Tropsch——SynthesisinaFixedBedReactor
Configuration
AnsariShahidHussain~andShahidNaveed
,.CenterforAdvancedStudiesinEnergy,NationalUniversityofSciences&Technology,~lamabad44000,Pakistan
2.FaculytofChemicalEngineering,UniversiytofEngineeringandTechnology,Lahore54000,Pakistan
Received:August25,2014 /Accepted:November13,2014 /Published:February28,2015
Abstract:A seriesofexperimentswereperformedonindigenouslysynthesizedcatalystpalletsofcobaltasavery activemeta1on
ceramicsupport 1ikeSiC,AI2O TiO2inafixedbedreactorconfigurationwithanaim tostudythecatalystactivity selectivity,
chemicalkinetics,designflexibility,temperature,pressurebycharacteristicsdiffusiondistance.Catalystpalletswerepreparedand
thencharacterizedbyN2adsorption,X—rayDiffraction,ScanningElectronMicroscope,andTemperatureProgrammedReduction.
TheresultsshowedtheBrunauer.EmmettandTellerareaofSiC wasthelowestamongthethreesuppo~spreparedfortesting.
However,itsreducibilityshowedimprovementwith useofcobaltacetate。asaprecursor.ratherthancobaltnitrates.Mechanical
strengthandbehaviorwascheckedbythehardnesstestingmachine.FischerTropschfFT1synthesisexperimentswereperofmr edin
thefixedbedreactorsetat450—500K and2.3—2.5MPausingsyntheticgashavingH,/C0 ration= 2.0.FT synthesisshowedthat
cobalt/siliconcarbidecatalystgiveshi CO conversionandlowermethaneselectivity,comparedtoCo/AI,O1andCo/TiO2,aswell
ashighC5 selectivityofalmost90%.Moreover.itsstabilitywasenhancedbytheadditionofZr0,aswithoutthisaddition,the
Co/SiC interactionsareweakerandcancausecarbonsintering.andthus。thedeactivationratetoincrease.
Keywords:Fischer-Tropsch·synthesis,cleancoal,alternateliquidfuel、metalliccatalysts syngas
1.Introduction
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