Optimum High-Quality Ceramic Support like SiC, AI203 & TiO2 for Cobalt as a Very Active Metal for Fisher-Tropsch-Synthesis in a Fixed Bed Reactor Configuration.pdfVIP

Optimum High-Quality Ceramic Support like SiC, AI203 & TiO2 for Cobalt as a Very Active Metal for Fisher-Tropsch-Synthesis in a Fixed Bed Reactor Configuration.pdf

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Optimum High-Quality Ceramic Support like SiC, AI203 & TiO2 for Cobalt as a Very Active Metal for Fisher-Tropsch-Synthesis in a Fixed Bed Reactor Configuration.pdf

JournalofEnergyandPowerEngineering9(2015)141—148 doi:10.17265/1934.8975/2015.02.003 一 塔 Optimum High—QualityCeramicSupportlikeSiC,AI203& Ti02forCobaltasaVeryActiveMetalfor Fisher--Tropsch——SynthesisinaFixedBedReactor Configuration AnsariShahidHussain~andShahidNaveed ,.CenterforAdvancedStudiesinEnergy,NationalUniversityofSciences&Technology,~lamabad44000,Pakistan 2.FaculytofChemicalEngineering,UniversiytofEngineeringandTechnology,Lahore54000,Pakistan Received:August25,2014 /Accepted:November13,2014 /Published:February28,2015 Abstract:A seriesofexperimentswereperformedonindigenouslysynthesizedcatalystpalletsofcobaltasavery activemeta1on ceramicsupport 1ikeSiC,AI2O TiO2inafixedbedreactorconfigurationwithanaim tostudythecatalystactivity selectivity, chemicalkinetics,designflexibility,temperature,pressurebycharacteristicsdiffusiondistance.Catalystpalletswerepreparedand thencharacterizedbyN2adsorption,X—rayDiffraction,ScanningElectronMicroscope,andTemperatureProgrammedReduction. TheresultsshowedtheBrunauer.EmmettandTellerareaofSiC wasthelowestamongthethreesuppo~spreparedfortesting. However,itsreducibilityshowedimprovementwith useofcobaltacetate。asaprecursor.ratherthancobaltnitrates.Mechanical strengthandbehaviorwascheckedbythehardnesstestingmachine.FischerTropschfFT1synthesisexperimentswereperofmr edin thefixedbedreactorsetat450—500K and2.3—2.5MPausingsyntheticgashavingH,/C0 ration= 2.0.FT synthesisshowedthat cobalt/siliconcarbidecatalystgiveshi CO conversionandlowermethaneselectivity,comparedtoCo/AI,O1andCo/TiO2,aswell ashighC5 selectivityofalmost90%.Moreover.itsstabilitywasenhancedbytheadditionofZr0,aswithoutthisaddition,the Co/SiC interactionsareweakerandcancausecarbonsintering.andthus。thedeactivationratetoincrease. Keywords:Fischer-Tropsch·synthesis,cleancoal,alternateliquidfuel、metalliccatalysts syngas 1.Introduction

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