涂建双金属负载中空球型催化剂的制备及性能研究：.doc

双金属负载中空球型催化剂的制备 及性能研究 摘要 ： ABSTRACT Water resource is necessary for the human being, our production and daily life cannot run without it. However, tons of wastewater were produced during these processes, and the wastewater treatment is a huge task we are facing. During dying and finishing processes lots of water was needed, and produced amounts of dye wastewater. And the trouble is that dye wastewater is becoming more difficult to treatment because the dye molecule gets more and more stable. The dye wastewater is difficult to treatment, and has high colority, the traditional ways is inefficiency during the treatment. Wet air oxidation is an effective method to treat the dye wastewater, but the critical conditions (high temperature, high pressure) limit its application. Catalytic wet air oxidation moderates the conditions, and catalyst can degrade the reaction activation energy and accelerate the reaction.In this paper, we prepared hollow silica spheres and catalysts, including single component catalysts, and bi-components catalysts, such as CuO/SiO2 , CuO-ZnO/SiO2, which using to degrade Acid brilliant scarlet 3R solution by H2O2. The main contents include: Carbon template was synthesized under hydrothermal condition using glucose solution, and ethyl silicate was hydrolyzed around the carbon template with the help CTAB, and shaped core-shell particles, then we got hollow silica spheres after dried and calcinated. The structure of hollow silica spheres was studied by SEM, TEM etc. Single component catalysts were prepared by impregnation method using hollow silica spheres as supporter. Bi-component catalysts CuO-CeO2/SiO2、CuO-Fe2O3/SiO2、CuO-MnO2/SiO2、CuO-ZnO/SiO2 were prepared by impregnation method. At the conditions: pH=3.5, T=60℃, catalyst dosage 6 g/L, we studied the effect of catalytic degradation reaction. The result showed that Ce element doped reduced Cu2+ ion leaching, Fe, Zn elements doped improved the effect of degradation, especially the Zn element. Key