氨法碳捕集过程中氨逃逸控制.pdfVIP

第 65 卷 第 10 期 化 工 学 报 Vol.65 No.10 October 2014 2014 年 10 月 CIESC Journal ·4086 · 氨法碳捕集过程中氨逃逸控制 马双忱，陈公达，马宵颖，郭蒙，韩停停，宋卉卉 （华北电力大学环境学院，河北保定 071003 ） 摘要：本研究致力于解决再生氨法碳捕集过程中氨的逃逸问题。根据实验室前期研究结果，分别选取抑制效果较 好的丙三醇和 Co( Ⅱ)进行实验研究。详细分析了其抑制氨逃逸机制，并通过 IR 、XRD 等对物种进行分析。同时 探究其对再生氨法碳捕集过程 CO2 脱除效率和解吸效果的影响。实验结果表明，丙三醇和 Co( Ⅱ)对氨逃逸均有 较好的抑制效果，平均抑氨效率在 40% 以上。二者的引入对吸收过程均无显著影响，且Co( Ⅱ)能使 CO2 解吸比 例提高。 关键词：二氧化碳捕集；氨法；吸收；控制 DOI ：10.3969/j.issn.0438-1157.2014.10.044 中图分类号：X 511 文献标志码：A 文章编号：0438—1157 （2014 ）10—4086—08 Ammonia escape control in carbon dioxide capture using ammonia method MA Shuangchen, CHEN Gongda, MA Xiaoying, GUO Meng, HAN Tingting, SONG Huihui （School of Environment, North China Electric Power University,Baoding 071003, Hebei, China ） Abstract: This paper focuses on ammonia evaporation in ammonia-based CO2 capture. Based on our previous research, glycerol and Co( Ⅱ) with promising effect on controlling ammonia escape were studied. The mechanisms of controlling ammonia escape using glycerol and Co( Ⅱ) were analyzed with IR, UV, XRD and the impact on CO2 removal and desorption was investigated. Both glycerol and Co( Ⅱ) could control ammonia escape with average efficiency of above 40%. Glycerol and Co( Ⅱ) had no significant effect on absorption of carbon dioxide, while Co( Ⅱ) could promote desorption of CO2 . Key words: CO2 capture; ammonia method; evaporation; control 引 言 减排工作的一个重要研究方向[6-8] 。氨法脱碳副产物