添加秸秆类生物质对长平煤灰熔融特性的影响.pdfVIP

第65 卷 第12 期 化 工 学 报 Vol.65 No.12 December 2014 2014 年12 月 CIESC Journal ·4948 · 添加秸秆类生物质对长平煤灰熔融特性的影响 唐建业，陈雪莉，乔治，刘爱彬，王辅臣 （华东理工大学煤气化及能源化工教育部重点实验室，上海市煤气化工程技术研究中心，上海 200237 ） 摘要：借助高温热台显微镜、扫描电子显微镜-能谱仪、灰熔点仪和 X 射线衍射仪考察了添加稻草和棉秆两种秸 秆对长平煤灰熔融特性的影响。研究结果表明添加两种秸秆都能有效地降低长平煤灰的熔融温度。在高温弱还原 性气氛下，长平煤灰主要矿物组成为耐熔性石英和莫来石，而添加秸秆后产生了白榴石、尖晶橄榄石、钙长石等 低温共熔化合物，使长平煤灰熔点降低。不同灰的高温熔融图像表明，煤灰在熔融过程中由于受热而使固相持续 软化，形成了不利于难熔物分解的高黏度熔体。而煤和稻草的混合灰在熔融时形成了易发生流动的低黏度熔体， 能够促进矿物质发生反应而更易熔融。 关键词：煤；秸秆类生物质；灰熔融特性；矿物质；高温熔融图像 DOI ：10.3969/j.issn.0438-1157.2014.12.041 中图分类号：TK 6 文献标志码：A 文章编号：0438—1157 （2014 ）12—4948—10 Influence of agro-biomass addition on Changping coal ash melting characteristics TANG Jianye, CHEN Xueli, QIAO Zhi, LIU Aibin, WANG Fuchen (Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education , East China University of Science Technology, Shanghai Engineering Research Center of Coal Gasification, Shanghai 200237, China) Abstract ：The effects of rice straw (DC) and cotton stalk (MG) addition on Changping (CP) coal ash melting characteristics were studied with high-temperature optical microscopy, scanning electron microscopy coupled with energy dispersive spectrometer (SEM-EDS), standard ash fusion temperature (AFT) tests and X-ray diffraction (XRD) analyses. The AFT of CP coal could be reduced effectively by adding both agricultural residues. In weak reducing atmosphere at high temperature, refractory mullite and quartz were main minera