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_ Abstract
Abstract
JunfangCai (MajorinP冲sicalChemistry)
DirectedbyProfessorMinghuaLiu
Themonolayerbehaviorsair/waterinterfacesandLangmuir-Blodgett(LB)filmsof
threegroupsofnon-typicalamphiphileshavebeenstudied.Thesecompounds
include(1)2-phenyibenzimidazole(PhBz)and2-(2-pyridyl)benzimidazole
(PyBz)
(2) 2-(2-hydrox必enzylidene)-aminobenzimidazole(HBA) and 2-(2-
hydroxynaphthyli-dene)-aminobenzimidazole(HNA)and (3)poly(methylenebis-
(benzimidazole对)田BzCa)withthelengthofmethylenerunningrfom0to8.
Thesecompoundscannotformstablemonolayersatpurewaterinterfacebecause
oftheirsrtonghydrophilicity,whiletheyallcanformstablemonolayersatinterfaces
whenthesubphasescontainingvariousconcentrationsofsilverions.Thesurface
pressure-areaisotherms(ac-A)changesignificantlywiththechangesof
concenrtationsofAg(I)inthesubphases.WhentheconcentrationsofAg(I)are
greaterthan10m城 ths-rz-Acurvewouldnotchangesignificantly.Interestingly,
thesemoleculescannotformstsblemonolayersatinterfaceswhenthesubphases
containingothermetalions.Similarmonolayerbehaviorsofthemwereobservedby
BAM.ThesemoleculescanallbetransferredontosolidplatesasX-ytpeLBfilms
byhorizontalliftingmethod,theseLBfilmswerecharacteredbymeansofLTV,IR,
XRD，XPS,andTEM.
Afterhavingbeenstudiedthroughseveralways,itisfoundthatthemonolayers
areformedthroughinsituformationofcoordinationpolymerwiththeAg(I)existin
Abstract
themainchain,thefilmscanbetransferredontosolidsubstrateswithregularlayer
structures.ExposuretoUVlightorHC1gascaninducenanoparticalesintheLB
films.Ourinvestigationonthepoly(methylenebis(benzimidazoles))(BBzCn)showed
thatwhenthelengthbetweenthetwobenzimidazolesisequaltoorlargerthan
hexamethylene,thecompoundc
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