Iron(III)-Mediated AGET ATRP of Methyl Methacrylate in the Absence of Additional Ligand.pdfVIP
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Iron(III)-Mediated AGET ATRP of Methyl Methacrylate in the Absence of Additional Ligand.pdf
Open Journal of Polymer Chemistry, 2012, 2, 99-104
/10.4236/ojpchem.2012.23013 Published Online August 2012 (http://www.SciRP.org/journal/ojpchem)
Iron(III)-Mediated AGET ATRP of Methyl Methacrylate in
the Absence of Additional Ligand
*
Svetlana A. Bulgakova , Evgeniya S. Volgutova, Irina E. Khokhlova
Research Institute of Chemistry, University of Nizhny Novgorod, Nizhny Novgorod, Russia
*
Email: sbulg@ichem.unn.ru, sbulg@mail.ru
Received June 3, 2012; revised July 1, 2012; accepted July 12, 2012
ABSTRACT
The atom transfer radical polymerization on the mechanism of activator generation by electron transfer (AGET ATRP)
of methyl methacrylate (MMA) in N,N-dimethylformamide (DMF) in the presence of the catalytic systems, namely,
CCl -FeCl -1-acetyl-2-phenylhydrazine (APH) and CCl -FeCl -ascorbic acid (AA) is reported. The living feature of
4 3 4 3
this process was confirmed by obtaining well-defined polymers with controlled molecular weight, narrow molecular
weight distribution, and a chain-extension experiment. Both reducing agents, an APH as well as an AA, possess the
equal kinetic activitis.
Keywords: Atom Transfer Radical Polymerization; Methyl Methacrylate; Iron; Ligand
1. Introduction catalyst, namely, from a transition metal-ligand complex,
which is used usually at concentrations from 0.1 to 1
Atom transfer radical polymerization is acknowledged to
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