钛网电极的光催化和光电催化对亚甲基蓝脱色率的影响-毕业论文.doc

摘 要 实验采用微弧氧化技术制备了钛网电极，以亚甲基蓝为待解降液，考察了微弧氧化制备条件如电解质种类、电解质浓度、微弧时间对亚甲基蓝的光催化和光电催化的脱色情况。结果表明，6 g/l的Na3PO4和5 min的微弧时间是制备钛网的最佳条件。 采用微弧氧化负载Cu2+法修饰钛网电极。当Cu2+的浓度为0.01 mol/l，微弧氧化时间7 min时，光催化和光电催化对亚甲基蓝的脱色率分别达到42.72%和42.26%。另外，考察了多种因素对亚甲基蓝光电催化的脱色率影响。根据单因素优化的步骤，最终确定了在5 mg/l的亚甲基蓝，0.01 mol/l的硫酸钠溶液，1.5 cm的电解间距，3.0 V的外加电压以及pH为5的情况下，光电催化对亚甲基蓝的脱色率达到45.0%。 以甲醛为目标降解物，光照催化120 min，最佳性能的钛网对它的光催化和光电催化降解率分别为30.12%和21.90%。 关键词：微弧氧化；铜掺杂；钛网电极；甲醛 Abstract Titanium mesh electrode supported on titanium substrates were prepared by micro-arc oxidation. Experiment adopted methylene blue as the test material. Photocatalytic and photoelectrocatalytic decoloring rate of methylene blue were carried out with an aim to inspect the influence of preparation conditions of TiO2 such as electrolyte, electrolyte con-centration, and micro-arc time. The results showed that 6 g/L of Na3PO4 and 5min micro-arc time is the best condition for the preparation of TiO2 thin films . The method of micro-arc oxidation load Cu2+ was determined to modify titanium mesh electrode When the concentration of Cu2 + was 0.01 mol / L and micro-arc oxidation time was 7 min , the photocatalytic and photoelectric catalytic decoloration rate of methylene blue can reach 42.72% and 42.26% ,respectively. Some relevant factors influencing photoelectric catalytic decoloration rate of methylene blue were investigated. After single factor optimization, we drew a conclusion that the degradation of methylene blue rate reached 45.0% under the circumstances of 5 mg/l methylene blue and 0.01 mol/l sodium sulfate solution, 1.5 cm electrolytic spacing, 3.0 V applied voltage ,pH of 5. Finally formaldehyde was studied, the photocatalytic degradation attained 30.12% and photoeletrocatalytic degradation reached 21.90% in 2 h. Kewords: micro-arc oxidation; copper doping; titanium mesh electrode ;formaldehyde; 目　录 摘 要 I Abstract II 目　录 III 1 绪论 1 1.1 引言 1 1.2 光催化技术 2 1.2.1 TiO2光催化剂的性质 2 1.2.2 TiO2降解甲醛的机理 3 1.2.3 影响光催化活性的因素 4 1.3 微弧氧化技术 5 1.3.1