表面张力Drop_Impact_and_Spreading_on_Surfaces_of_Variable_Wettability.pptVIP

Swansea 2007 Results - Streamlines Solid 2 less wettable Qualitative agreement Swansea 2007 Results – Velocity Profiles Tangential (slip) velocity varies around its equilibrium value of u=9.8. Fluxes are both in and out of the interfacial layer. Overall mass is conserved. Swansea 2007 Further Work Compare results with molecular dynamics simulations. Devise experiments to test predictions. Fully investigate periodic case. Single transition investigation is in: Sprittles Shikhmurzaev, Phys. Rev. E 76, 021602 (2007). Swansea 2007 Thanks! Swansea 2007 Numerical Analysis of Formula for J Shapes are numerical results. Lines represent predicted flux Swansea 2007 Interface Formation Equations + Input of Wettability Transition in wettability centred at x=y=0. Input of wettability Swansea 2007 Surface Equation of State Break-up Dynamic wetting Swansea 2007 Deviation of The Actual Contact Angle = Non Equilibrium Surface Tensions Left: Curtain Coating Experiments (+) vs Theory (lines) Blake et al 1999 Wilson et al 2006 Right: Molecular Dynamics Koplik et al 1989 Swansea 2007 Comparison of Theory With Experiment Perfect wetting (Hoffman 1975; Str?m et al. 1990; Fermigier Jenffer 1991) Partial wetting (□: Hoffman 1975; ?: Burley Kennedy 1976; ?, ?, ?: Str?m et al. 1990) It has been shown that the theory is in good agreement with all experimental data published in the literature. Swansea 2007 Mechanism of Relaxation Comparison of the theory with experiments on fluids with different viscosity (1.5-672 cP) confirms that the mechanism of the interface formation is diffusive in nature (J. Coll. Interface Sci. 253,196 (2002)). Estimates for parameters of the model have been obtained, in particular, showing that for water-glycerol mixtures one has: where * Swansea 2007 Second Harmonic – Large Deformation (cont) Aspect ratio of the drop as a function of time. A damped wave. Swansea 2007 Fourth Harmonic – Large Deformation For Re=100, f4 = 0.9 Swan