含磷苯并恶嗪的合成、表征及其阻燃改性环氧树脂分解.docVIP

含磷苯并噁嗪的合成、表征及其阻燃改性环氧树脂 赵朋，张楠，王标兵* （常州大学材料科学与工程学院，常州 213164） 摘要：以9，10-二氢-9-氧杂-10-磷杂菲-10-氧化物UL-94垂直燃烧试验、热重分析法和动态力学性能测试分别研究它们的阻燃性能、热性能和机械性能。结果表明，环氧树脂样条的阻燃性能显著提高，随着环氧树脂中苯并噁嗪含量的增加，样条的储能模量和玻璃化温度呈降低趋势。 关键词：含磷苯并噁嗪；环氧树脂；阻燃性 Synthesis and Characterization of Polybenzoxazine containing Phosphorus and its Flame Retardant Effect on the Epoxy Resin Peng Zhao, Nan Zhang, Biaobing Wang* (School of Materials Science and Engineering, Changzhou University, Changzhou 213164) Abstract: A novel polybenzoxazine containing phosphorous has been successfully prepared using 9, 10-dihydro-9-oxa-10-phosphaphenanthrene (DO