新型发光高分子材料的合成与表征.pdfVIP

簿±磊搬告 鹣等。 一直得到高分子科学家的青睐。具有这样结构的高分予目前开始应用到液晶高分子、发 transfer 垂峦萎豢合豹方式f缸歉魏Atom radical 要比较菏刻的反应条件，而且获得coil总是含商烯烃类(如苯乙烯，丙烯酸醮类)的聚 合物段。本文采取简单的缩合聚合的方法，获得了一种新的具有rod—coil结构的发光高 分子。结果显示获得聚合物能够问时其肖溶液和固体薄膜发光，而且发光位置变化不大， 该耪辩辘够狠露荔露溃疆努翠鹣方式袋貘，在玻璃表瑟滋嚣垂缀装瑗象。这个王{乍搽索 了一条糖的制镰具有rod．coil结构的发光高分予的路径。 关键词：功能化，发光聚懿酯，rod-coil结构，原子转移自由基聚合，缩合聚合 博士磊鬟誊 Abstract Sincetheexcellentworkfromthe AJand．MacDiarmidAGthe onthe Heeger progress researchof hasbeenachieved kindsof are conjugatedpolymers significantly．These polymer alsonamedconductiveor fluorescentmaterialsandused infields polymerpolymeric widely and of transistors． of been the emissionhas intensiveinterestfrom Conjugatedpolymer丽thpropertylight paid scienceandindustriatfield． withthe cancombinethe of Conjugatedpolymer property advantagesgeneralpolymers and haveobviousdifferentstructurecharacterfromthatoftheclassic semiconductors，They delocalizedthedirectionofthemain—chainol、 cloud”is polymer．The“electron along ina thanlocalized area。 macromolecule，ratherspecial It isonenew and tomake concepttendency generalpolymers introducethe of emissiontoclassic oftenused light polymers。Two especially property toachie