水基硼系多功能添加剂的制备.doc

摘要 洛阳理工学院毕业设计（论文） PAGE IV PAGE 29 水基硼系咪唑啉型多功能添加剂的制备 环境工程与化学系 陆艮雷 指导老师 王永刚 摘 要 在实验室的条件下制备了一种水溶性的硼酸二乙醇胺酯，即水基硼咪唑啉型多功能添加剂, 该物质是一种多功能添加剂，具有优良的抗磨、抗氧、抗腐蚀作用。本文通过试验研究，介绍了硼酸酯的种类、合成、应用等。首先研究了硼酸二乙醇胺酯的合成，以硼酸、二乙醇胺或β-羟乙基乙二胺为反应物，甲苯作为溶剂，通过检测反应生成的水的量和红外检测仪的检测结果，确定了合成硼酸二乙醇胺酯的最佳工艺；然后利用该产物与癸二酸按照不同的比例配制，分别测定不同比例下的水溶性，得到硼酸二乙醇胺酯与癸二酸的复合物最佳比例，然后通过硅烷偶联剂改性，即利用该复合物分别与自来水、N-(β-氨乙基)-γ-氨丙基三甲氧基硅烷溶液及其水溶液来测定硼酸二乙醇胺酯的水溶性，进一步增强水基硼添加剂在生产使用过程中的耐蚀性、抗氧化性和耐磨性等作用。 关键词：水基硼咪唑啉型多功能添加剂 最佳工艺 水溶性 硅烷改性 Water-based boron imidazoline multifunctional additive preparation ABSTRACT Prepared under laboratory conditions, a water-soluble boric acid diethanolamine ester and β-hydroxyethyl ethylenediamine ester, i.e.,water-based boron imidazoline multifunctional additive, the substance is a multifunctional additive having excellent antiwear, antioxidant, anti-corrosion effect. In this paper, experimental research, introduced the borate species, synthesis, application and so on. First studied diethanolamine borate ester, boric acid, diethanolamine, or β-hydroxyethyl ethylenediamine as reactants, toluene as a solvent, water of reaction by detecting the amount and the detection result of the infrared detector to determine the diethanolamine borate ester synthesis optimum; then use this product with a ratio of sebacic acid according to the different preparation, different ratios were measured solubility in water, to obtain borate ester with sebacic acid diethanolamine complex of optimal ratio, and a silane coupling agent, namely the use of the complex, respectively, and water, N-(β-aminoethyl)-γ-aminopropyl trimethoxy silane and the aqueous solution was measured by a water-soluble boric acid ester of diethanolamine, further enhance the water-based boron additives used in the production process of corrosion resistance, oxidation resistance and abrasion resistance and so on. Keywords：Water-based multifunctional additive boron imidazoline Best process Water-soluble Silane-modified 目录  TOC \o 1-3 \h \z \u  HYPERL