TMDs综述.docxVIP

二维过渡金属硫族化合物及在光电子器件中的应用 曾为 材料学院 西北工业大学 2014100322 摘要：由单层过渡金属硫族化合物(Transition metal dichalcogenides，TMDCs)构成的类石墨烯材料是一种新型二维层状化合物，近年来以其独特的物理、化学性质而成为新兴的研究热点。本文综述了近年来二维TMDCs常见的几种制备方法，包括以微机械力剥离、锂离子插层和液相超声法等为主的“自上而下”的剥离法，以及以高温热分解、化学气相沉积等为主的“自下而上”的合成法；介绍了其常用的结构表征方法，包括原子力显微镜(AFM)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)和拉曼光谱等；概述了二维TMDCs的紫外-可见(UV-Vis)吸收、荧光发射等基本光物理性质及其相关机理；总结了二维TMDCs在二次电池、场效应晶体管、传感器、有机电致发光二极管和电存储等光电子器件领域的应用原理及其研究进展，展望了这类新型二维层状化合物的研究前景。 关键词：过渡金属硫族化合物；层状化合物； 材料制备； 结构表征；光物理性质；光电子器件 Two-dimensional transition metal chalcogenides and applications in electronics and optoelectronics devices Abstract: Two-dimensional(2D) Transition metal dichalcogenides (TMDCs), which is composed of a monolayer of TMDCs, is a new two-dimensional layered material that has attracted considerable attention recently because of its unique structure and optical and electronic properties. Here we first review the methods used to synthesize 2D TMDCs.“Top-down” methods include micromechanical exfoliation, lithium-based intercalation and liquid exfoliation, while the“bottom-up”approaches covered are thermal decomposition and hydrothermal synthesis. We then discuss several methods used to characterize the 2D TMDCs, such as atomic force microscopy (AFM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and Raman spectroscopy. We describe the UV-Vis absorption and photoluminescent properties of 2D TMDCs and their related mechanisms. Finally, we summarize the application of 2D TMDCs in various optoelectronic devices such as secondary batteries, field-effect transistors, sensors. The application principles and research progress are discussed, followed by a summary and outlook for the research of thisemerging 2D layered nanomaterial. Key Words: Transition metal dichalcogenides; 2D layered material; Material synthesis; Structure characterization; Photophysical property; Optoelectronic device 1 引 言 近年来随着石墨烯等二维层状纳米材料研究热潮的兴起[1-3]，一类新型的二维层状化合物——过渡金属硫族化合物(Transition metal dichalcogenides，TMDCs)