介孔三氧化二铝的制备及吸附性能研究报告.docVIP

洛阳理工学院毕业设计（论文）  PAGE I 洛 阳 理 工 学 院 毕 业 论 文 介孔三氧化二铝的制备及吸附性能研究 姓 名 朱泽楷 系 （部）环境工程与化学系 专 业 环境工程 指导教师 陈华军 2013年 6月 2日 洛阳理工学院毕业论文  PAGE IV 介孔三氧化二铝的制备及吸附性能研究 摘 要 印染废水色度高、组成复杂、有机物含量高，是较难处理的工业废水之一，而对废水中染料的脱色是印染废水处理过程中首先需要解决的关键问题。吸附法因其操作简单、方便有效等特点，被广泛的应用到印染废水的脱色处理中。 本文采用以PEG（2 000）为模板，Al(NO3)3·9H2O为原料，CO(NH2)2为沉淀剂，在水热条件下的方法合成Al2O3介孔纤维，研究Al2O3介孔纤维对亚甲基蓝的吸附特性，包括吸附动力学和吸附等温线。 介孔Al2O3对亚甲基蓝的吸附等温式符合Freundlich等温式，不遵循Langmuir单分子层等温吸附方程，遵循BET多分子层吸附等温方程，故吸附为多分子层吸附。 在吸附动力学的五种模型中，Al2O3对亚甲基蓝的吸附符合准二级吸附动力学方程，相关系数R2大于0.99。 关键词: 介孔，三氧化二铝，制备，水热法，亚甲基蓝染料，吸附 Preparation and adsorption properties of activated alumina ABSTRACT Printing and dyeing wastewater with high, complex composition, high organic content, is one of the industrial wastewater is difficult to be treated, and the decolorization of dye wastewater is a key issue and must be solved in the process of printing and dyeing wastewater treatment. Adsorption method because of its simple operation, convenient and effective, is widely applied to the decolorization of dyeing wastewater. This paper uses PEG (2000) as template, Al (NO3) 3 · 9H2O as raw materials, CO (NH2) 2 as precipitant, under hydrothermal conditions of synthesis of Al2O3 mesoporous fiber, Al2O3 mesoporous fiber on the adsorption characteristics including adsorption kinetics and adsorption isotherm. AL2O3 on the isothermal adsorption of methylene blue in accordance with Freundlich isotherm, do not follow the Langmuir monolayer adsorption isotherm equation, follow the BET multi molecular layer adsorption isotherm equation, the adsorption of multimolecular layer adsorption. In the five model the adsorption kinetics of Al2O3 on the adsorption of methylene blue, with the two stage adsorption kinetic equation, correlation coefficient R2 is greater than 0.99. Keywords: mesoporous，Al2O3，oxidation，hydrothermal synthesis，methylene blue，adsorbention 目录 TOC \o 1-3 \t \h \z \u  HYPERLINK \l _Toc31192 前　言  PAGEREF _Toc31192 1  HYPERLINK \l _Toc21