GCMS测定86种农残.pptVIP

Introduction 1 Experimental Figure 1. An overlay of two total ion chromatograms TIC with 100pg a and 500pg b of each of the pesticides injected. Conclusion This application note shows that PerkinElmer Clarus 600 GC/MS system meets all the requirements for reliably detecting 86 pesticides in a single run down to 10 pg. This includes minimum detection limits and calibration requirements. All pesticides determined passed the 15 %RSD requirements. Correlation coefficients are included in Table 2 to show individual pesticide performance. The engineers in Beijing Food Lab used QuEChERS and Japan Positive Carb/NH2 method to handle a variety of the food samples. QuEChERS is good at preparing 慶lean?food samples, such as cabbage, pear, rice, corn and flour. Japan Positive Carb/NH2 method has less co-extracted food matrix, so it gives better baseline. Japan Positive Carb/NH2 method is good at preparing 慸irty?food samples, such as instant coffee. This GC/MS method allows the engineers in Beijing Food Lab to measure many samples at low concentrations in a variety of food matrices. ? Result and discussion 2 6 3 Reliably Detect 86 of Pesticides in a Single Run Down to 10pg with GC/MS in the Beijing Food Lab Meng Yuan, PerkinElmer, Inc., Shelton, CT USA Hui Xiao, Mengyin Sun and Yasong Zhao, Beijing Food Lab, Beijing, P.R. China Pesticides are dangerous in food. Accurate measurements are necessary to assure uncontaminated food. Most standard methods recommend that pesticides are analyzed on a gas chromatograph GC with element selective detectors, such as ECD Electron Capture Detector and FPD Flame Photometric Detector . These detectors do not provide sufficient information to confirm a pesticide抯 presence with confidence, so it is difficult to eliminate false positives. A mass spectrometer MS provides additional information. False positives may be eliminated with the spectral deconvultion software, Automated Mass Deconvolution and Identification Sys