浦东新区环境空气重金属浓度及其分布特征-环境监控与预警.docVIP

上海浦东新区环境空气重金属污染特征及来源解析 丁溪萍，徐建平 上海市浦东新区环境监测站，上海200135 摘要：选择浦东新区城区点和郊区点，收集2012年3月至2013年2月TSP样品，利用双酸消解原子荧光法、ICP法分析了样品中的13种元素。结果表明，除As略超标外其他元素环境空气浓度均达标。质量浓度排在前三位的元素是Fe、Sn、Zn，占样品中金属总量的83%-87%；质量浓度排在末四位的元素是Ni、Cr、As、Cd，占样品中金属总量的1%-2%。通过EPA PMF5.0模型运算结果，在城区中6个因子贡献比最高的31.5%为Sn+Fe+Mn，贡献比最低的2.1%为Hg；在郊区中6个因子贡献比最高的36.4%为Pb+Cu，贡献比最低的9.2%为Fe+Sn+Mn。浦东新区富集因子E小于等于10的元素有Cr、V、Ba、Mn、Ni、Fe、Hg城、Cu郊、As；富集因子E大于10的元素有Hg郊、Cu城、Zn、Pb、Cd、Sn。 关键词：浦东新区；环境空气；重金属；正定矩阵因子分析；富集因子 Pollution and source of heavy metals in Pudong New Area ambient air DING Xi-ping, XU Jian-ping ((Pudong?New?Area?Environmental?Monitoring?Station,?Pudong?New?Area，?Shanghai?200135，China Abstract:Samples of TSP were collected from pudong new area of the city and suburbs in March 2012 to February 2013 and the 13 kinds of elements in the samples were analyzed by atomic fluorescence and double acid ICP method . The results showed that: ambient air concentrations of other elements were met the standard except As slightly overweight. Mass concentration of the top three elements were Fe, Sn, Zn accounting for 83%-87% of the total sample of metal; mass concentration of the elements at the end of the four were Ni, Cr, As, Cd, 1% -2% of the total metal. By EPA PMF5.0 model calculation results, the contribution of the 6 factors in the urban area were 31.5% to Sn+Fe+Mn and the lowest 2.1% for Hg; the highest contribution ratio of 36.4% in the suburbs of 6 factors were Pb+Cu and the lowest 9.2% for Fe+Sn+Mn. Enrichment factor E less than or equal to 10 were Ba, Mn, Ni, Cr, V, Cu, Fe, Hg城, As; more than 10 were Hg郊, Cu城, Zn, Pb, Cd, Sn. Key words: pudong new area; ambient air; Heavy metals; Positive definite matrix factor analysis; enrichment factor 国家在2012年2月29日发布了新的环境空气质量标准，增加了重金属控制指标[1]，国内对空气颗粒物中重金属也开展了短期监测研究[3][4][5][6]。为了了解浦东新区城郊环境空气中重金属浓度及分布特征，开展时间为一年2012年3月至2013年2月的13种重金属浓度调查监测，As、Hg用原子荧光法测定，Cd用石墨炉原子吸收分光光度法测定，其他元素用电感耦合等离子发射光谱法测定。 1 实验部分 1.1 主要仪器 美国PE公司的DV