城市湖泊水体邻苯二甲酸酯污染特征的研究.pdfVIP

城市湖泊水体邻苯二甲酸酯污染特征研究 体中DnBP的含量较高。 关键词：城市，湖泊，邻苯二甲酸酯，污染特征 lI 城市湖泊水体邻苯二甲酸酯污染特征研究 Study of The Distribution Characteristics of Phthalate esters in Lake of the City Park Analytical Chemistry Name：Li yangjie Supervisor：Assodatc Professor Zengfeng ABSTRACT Phthalate esters(PAEs)are one of the most important worldwide pollutant in the environment．The study of the distribution characteristics of such substance in the lake of the city park is significant to human health and to know about the quality of the urball entironment． The concentrations and distribution characteristics of sixteen PAEs in the water samples collected in different functionaI districts of Guang,zhou city were measumd by U．S．EPA 8061 series methods under quality assurance(QA)and quality control (QC)．The results showed that the concentrations of total PAEs in the water samples ranged from 4．840∥g几～12．78肛g几，average concentration was 8．284∥l，L TOC ranged from 5．558 mg／L to 30．73 m∥L the concentrations of total PAEs in the solute ranged from 1．371∥班to 8．437∥班，average concentration was 4．982∥叽TOC ranged from 3．283 mg／L to 8．794 mg，L the concentrations of total PAEs in the granule ranged from 165．1ⅥeCg to 1069p眺and average concentration was 296．2“g／g．The DEHP,DnBP and DiBP were the predominance of PAEs in the watel samples． Refer to the standard of foreign country and compare the concentration of PAEs in the water of lake with other foreign rivers，we discover that the contamination of PAEs in lake of the Guangzhou park is dight．But the concentration of DnBP is very big． Key Words：city,lake，Phthalate Ester,distribution characteristic III 城市湖泊水体邻苯二甲酸酯污染特征研究 第1章前言 邻苯二甲酸酯(PhthalicAcid Esters，简称PAEs)又称酞酸酯，是世界上生 产量大、应用面广的人工合成有机化合物之一。PAEs可用作农药载体、驱虫剂、 化妆品、香味剂、润滑剂和去污剂的生产原料。PAEs用量最大是作为塑料增塑 剂，约占其总产量的80％，广泛用于聚乙烯、聚氯乙烯、聚丙烯、聚苯乙烯的生 产。PAEs是塑料高聚体中不可缺少的改性添加剂，用于增大塑料的可塑性和提 高塑料的强度，其含量可达高聚体本身的20％--50％[1-3】。此外，人工心脏瓣膜、 血管移植材料、子宫避孕器和血液注射器等直接与人体健康有关的医用器具以及 合成纤维纺织品抛光剂等也都含PAEs。 由于PAEs在塑料中呈游离状态，由氢键或范德华力联接，彼此保留各自相 对独立的化学性质[41。因此，随使用时间的推移，可转移到外环