第8章气体吸收 §8.2气液相平衡.pptVIP

一.The solubility of gas in the liquid At T and P, S + mixture of gases of A+B, intimate contact 。随着两者的不断接触，solute A from gas phase →transfer to liquid phase, until液相中solute达到un-saturation。 It is dynamic balance at the moment which concentrations of A are constant within L V, that is, the amount of molecules of A entering in L phase = the amount of molecules of A escaping from L phase. 从宏观上看，吸收过程终止，即气液两相达到相平衡。显然，此时A在液相中的浓度最大。 此浓度称为饱和浓度，或溶质A的溶解度CA※. ∴ Definition solubility: 1. Solubility curve ～溶解度曲线 Assume: that only one component is transferred between phases .