Development of EoS for Vapours Gases.pptVIP

Development of EoS for Vapours Gases P M V Subbarao Professor Mechanical Engineering Department I I T Delhi Models for Highly Bountiful Phase…..….. Behaviour of Vapour ? = interatomic potential, Joules. r = separation of molecules, nm (mean Free path). r? = equivalent “hard sphere” radius of molecule (overlap of electron clouds). At high T, high p, collisions in the repulsive part of ?– positive deviations from constancy. At low T, moderate p, collisions in the attractive portion of ? – negative deviations from constancy. P – v- T Relation Greatest need for EoS of saturated and superheated steam. R and a are constants. The is called as Rankine’s Equation of state, 1849. The specific volume of A vapour: v = f (p,T) P – v- T Relation Callender’s Characteristic Equation for saturated and superheated vapours. R and b are constants. c is a function of temperature and it is called as co-aggregation volume. The specific volume of A vapour: v = f (p,T) Pressure Volume Diagram Van der Waals EOS One of the oldest but most extensively used of the EOS of non ideal gases Any EOS model must reproduce graphs such as that of the previous a, b are the Van der Waals constants for the particular gas; for water: a = 0.5658 J-m3/mole2; b = 3.049x10-5 m3/mole, JO H A N N E S D . V A N D E R W A A L SThe equation of state for gases and liquidsNobel Lecture, December 12, 1910 I intend to discuss in sequence: (1) the broad outlines of my equation of state and how I arrived at it; (2) what my attitude was and still is to that equation; (3) how in the last four years I have sought to account for the discrepancies which remained between the experimental results and this equation; (4) how I have also sought to explain the behaviour of binary and ternary mixtures by means of the equation of state. Van der Waals EOS a, b are the Van der Waals constants for the particular gas; for water: a = 0.5658 J-m3/mole2; b = 3.049x10-5 m3/mole, Van der Waals Coefficients Gas a (Pa m3) B (