物理化学相平衡业 图片版.docVIP

相平衡 1。指出下列平衡系统中的组分数C，相数Φ及自由度F。 ①I2(s)与其蒸气成平衡； ②CaCO3(s)与其分解产物CaO（s）和CO2（g）成平衡; ③NH4HS(s)与其分解产物NH3（g）H2S（g）成平衡； ④任意量的NH3（g）,H2S(g)与NH4HS成平衡； ⑤I2在两互不相容的溶液H2O和CCl4中达到分配平衡。 3.用相率分析硫的相图中，各点，线及相区的相平衡关系及自由度。 7.水异丁醇系统液相部分互溶，在101.325KPa下，系统的共沸点为89.7℃，气（G）,液（l1）,液（l2）三相平衡时的组成ω（异丁醇）依次为：70.0%，8.7%，85.0%，今有350g水和150g异丁醇形成的系统在101.325KPa压力下，由室温加热，问： ①温度刚要达到其共沸点时，系统处于相平衡时存在哪些相？其质量各为多少？ ②当温度由共沸点刚有上升趋势时，系统处相平衡时存在哪些相？其质量各为多少？ 14.固态完全互溶，具有最高熔点的A-B二组分系统的相图如下，指出各相点的相平衡关系，各条线的意义，a,b样品的冷却曲线。 18.二元凝聚系统Hg-Cd相图示意如附图，指出各个相区的稳定相和三相线上的相平衡关系。 16.某A-B二组分凝聚系统相图如下： ①指出个相区稳定存在时的相; ②指出图中的三相线 ，哪几个相成平衡，相平衡关系如何？ ③绘出图中状态点为a,b,c三点样品的冷却曲线，并注明各阶段时的相变化。 20.A-B二元凝聚系统相图如下，标出图中各相区的稳定相，并指出图中的三相线及三相平衡关系。 steel bolts, screws and studs GB/T3098.6-2000 scope of this project are: 1, 2, 3 aluminium sheet curtain wall of glass curtain wall and the Aluminum plastic Board curtain wall 4, and stone curtain wall 5, and curtain wall buried pieces 6, and light steel points type glass rain canopy, and aluminum Board rain canopy 7, and aluminum Venetian 8, and outdoor advertising (containing roofing and the State surface advertising) 9 to spring glass door 10, and concrete structure and curtain wall between of layer between, and around fire seal blocking 11, and anti-mine 12, and daughter wall top processing 13, and pan light ming, engineering of tie construction 14, and buildings of deformation sewing (settlement sewing, and expansion joints,) 15, and After the detailed design drawings issued a wall embedded part is inconsistent with the tenderer needs to increase fixed curtain wall structure 16, decorative surfaces and decorative surface and joints between parts of other buildings facing sealing process, required to support the outer decoration of a hole, hole, plugging holes and so on. This works more decorative items, in order to ensure that the decoration construction progress and quality, trying to avoid construction does not ... Processing. After installation is comple