种子乳液聚合法备聚氨酯.doc

中州大学毕业设计（论文） 题目：种子乳液聚合法制备聚氨酯—聚丙烯酸酯复合种子乳液聚合法制备聚氨酯—聚丙烯酸酯复合In recent years, with the rapid development of industry, environment pollution is more and more attracted the attention of the people, the nations of the world are increasingly used in a variety of methods to suppress the volatile organic compounds (VOC) emissions, countries all over the green materials has become the direction of the hard. And in this way can avoid these problems. Polyurethane emulsion has been widely used in many fields, performance and even in some respects can be comparable with the solvent products, but water resistance, weather resistance and hardness, is unable to meet the requirements of wood coatings。Through seed emulsion polymerization or interpenetrating network technology, the performance on the complementary material compound together is one of the effective ways to improve the performance of emulsion. Acrylate has excellent weather resistance, chemical resistance and high hardness and luster, but wear resistance, cold resistance, adhesion is poorer, and polyurethane performed very well in these aspects. This article first through ontology and solution polymerization to synthesize polyurethane pre polymers, in neutral phase, adding vinyl monomer viscosity reduction, green organic hemp polyurethane was synthesized by solution, then this solution as the seed was prepared by emulsion copolymerization of acrylate monomer with brown shell structure of excellent polyurethane propionate compound solution, without removing the solvent, thus saving the cost, and reduced the pollution to the environment. In addition, this article also discusses the initiator concentration and type, the content of hydrophilic group, the concentration of the emulsifier and the impact on the emulsion polymerization process, the ratio between the core-shell, comonomer in the proportion of corneal hardness of soft monomer and hard monomer, mechanical strength, thermal stability, and the influence of latex p